Show simple item record 2017-08-07T11:53:25Z 2017-08-07T11:53:25Z
dc.title Codeposition of Particles: Role of Adsorption of the Electroactive Species. en
dc.type Artículo es
dcterms.abstract Cu-Al2O3 composite coatings were obtained from a 0.2MCu2+ and 0.6Mmonosodium glutamate electrolytewhose pHwas adjusted at different values in the 3–10 range. Particle charging behavior was studied through ζ-potential measurements and the potential of zero charge of the electrode was determined using Electrochemical Impedance Spectroscopy. Scanning Electron Microscopy was used to characterize coatings surface and to detect particle incorporation. The wt% of alumina in the deposits was estimated using Energy Dispersive Spectroscopy performed on their cross section. Under these experimental conditions high incorporation of particles into the copper matrix was observed, which was ascribed to the increased Cu2+ adsorption on Al2O3 surface induced by the presence of glutamate in the electrolyte. It was found that hydration forces strongly influence the codeposition of particles as proposed by Fransaer et al. The results were used to identify the relevant steps in the process and to develop a semi-empirical model. en
dcterms.extent 7 p. es
dcterms.issued 2016-11-08
dcterms.language Inglés es
dcterms.license Attribution-NonCommercial-NoDerivatives 4.0 International (BY-NC-ND 4.0) es
dcterms.subject Electroquímica es
dcterms.subject Alumina en
dcterms.subject Codeposition en
dcterms.subject Composite Coating en
dcterms.subject Copper Electrodeposition en
cic.version info:eu-repo/semantics/submittedVersion es Bengoa, L. N. es Pary, P. es Egli, Walter Alfredo es
cic.lugarDesarrollo Centro de Investigación y Desarrollo en Tecnología de Pinturas es
dcterms.subject.materia Ciencias Químicas es
dcterms.identifier.url Recurso Completo es
dcterms.identifier.other doi: 10.1149/2.0721614jes es
dcterms.isPartOf.issue vol. 163, no. (14) es
dcterms.isPartOf.series Journal of The Electrochemical Society es
cic.isPeerReviewed true es
cic.isFulltext true es


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