Preparation and characterization of a supported system of Ni2P/Ni12P5 nanoparticles and their use as the active phase in chemoselective hydrogenation of acetophenone

cic.institucionOrigenCentro de Investigación y Desarrollo en Ciencias Aplicadases
cic.isFulltexttruees
cic.isPeerReviewedtruees
cic.lugarDesarrolloCentro de Investigación y Desarrollo en Ciencias Aplicadases
cic.versioninfo:eu-repo/semantics/publishedVersiones
dc.date.accessioned2020-05-15T13:54:44Z
dc.date.available2020-05-15T13:54:44Z
dc.identifier.urihttps://digital.cic.gba.gob.ar/handle/11746/10557
dc.titlePreparation and characterization of a supported system of Ni2P/Ni12P5 nanoparticles and their use as the active phase in chemoselective hydrogenation of acetophenoneen
dc.typeArtículoes
dcterms.abstractNi2P/Ni12P5 nanoparticles were obtained by thermal decomposition of nickel organometallic salt at low temperature. The use of different characterization techniques allowed us to determine that this process produced a mixture of two nickel phosphide phases: Ni2P and Ni12P5. These nickel phosphides nanoparticles, supported on mesoporous silica, showed activity and high selectivity for producing the hydrogenation of the acetophenone carbonyl group to obtain 1-phenylethanol. This is a first report that demonstrates the ability of supported Ni2P/Ni12P5 nanoparticles to produce the chemoselective hydrogenation of acetophenone. We attribute these special catalytic properties to the particular geometry of the Ni–P sites on the surface of the nanoparticles. This is an interesting result because the nickel phosphides have a wide composition range (from Ni3P to NiP3), with different crystallographic structures, therefore we think that different phases could be active and selective to hydrogenate many important molecules with more than one functional group.en
dcterms.creator.authorCosta, Dolly Carolinaes
dcterms.creator.authorSoldati, Analía L.es
dcterms.creator.authorPecchi, Ginaes
dcterms.creator.authorBengoa, José Fernandoes
dcterms.creator.authorMarchetti, Sergio Gustavoes
dcterms.creator.authorVetere, Virginiaes
dcterms.identifier.otherdoi:10.1088/1361-6528/aab3a8es
dcterms.identifier.urlRecurso onlinees
dcterms.isPartOf.issuevol. 29, no. 21es
dcterms.isPartOf.seriesNanotechnologyes
dcterms.issued2018-03
dcterms.languageIngléses
dcterms.licenseAttribution-NonCommercial-ShareAlike 4.0 International (BY-NC-SA 4.0)es
dcterms.subjectMonodisperse nanoparticles of nickel phosphidesen
dcterms.subjectNi2Pes
dcterms.subjectNi12P5en
dcterms.subjectHydrogenationen
dcterms.subjectChemoselectivityen
dcterms.subjectAcetophenoneen
dcterms.subject.materiaCiencias Químicases

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