Dynamic laser speckle technique as an alternative tool to determine hygroscopic capacity and specific surface area of microporous zeolites

cic.isFulltexttrueen
cic.isPeerReviewedtrueen
cic.lugarDesarrolloCentro de Química Inorgánicaes
cic.lugarDesarrolloCentro de Investigaciones Ópticases
cic.lugarDesarrolloCentro de Investigación y Desarrollo en Ciencias Aplicadases
cic.versioninfo:eu-repo/semantics/acceptedVersionen
dc.date.accessioned2018-05-16T17:37:29Z
dc.date.available2018-05-16T17:37:29Z
dc.identifier.urihttps://digital.cic.gba.gob.ar/handle/11746/7429
dc.titleDynamic laser speckle technique as an alternative tool to determine hygroscopic capacity and specific surface area of microporous zeolitesen
dc.typeArtículoes
dcterms.abstractAdsorption phenomena have several technological applications such as desiccants, catalysts, sep- aration of gases, etc. Their uses depend on the textural properties of the solid adsorbent and the type of the adsorbed liquid or gas. Therefore, it is important to determine these properties. The most common measurement methods are physicochemical based on adsorption of N2 to determine the surface area and the distribution of pores size. However these techniques present certain limi- tations for microporous materials. In this paper we propose the use of the Dynamic Laser Speckle (DLS) technique to measure the hygroscopic capacity of a microporous natural zeolite and their modi ed forms. This new approach based on the adsorption of water by solids allows determine their speci c surface area (S). To test the DLS results, we compared the obtained S values to those calculated by di erent conventional isotherms using the N2 adsorption-desorption method.en
dcterms.creator.authorMojica Sepúlveda, Ruth Daryes
dcterms.creator.authorMendoza Herrera, Luis Joaquínes
dcterms.creator.authorGrumel, Eduardo Emilioes
dcterms.creator.authorSoria, Delia Beatrizes
dcterms.creator.authorCabello, Carmen Inéses
dcterms.creator.authorTrivi, Marcelo Ricardoes
dcterms.extent26 p.es
dcterms.hasPartInforme científico de investigador: Trivi, Marcelo Ricardo (2016-2017)es
dcterms.identifier.otherdoi:10.1016/j.apsusc.2018.03.231es
dcterms.identifier.urlRecurso onlinees
dcterms.isPartOf.issuevol. 447es
dcterms.isPartOf.seriesApplied Surface Sciencees
dcterms.issued2018-07
dcterms.languageIngléses
dcterms.licenseAttribution-NonCommercial-NoDerivatives 4.0 International (BY-NC-ND 4.0)*
dcterms.subjectDynamic laser speckleen
dcterms.subjectNitrogen physisorptionen
dcterms.subjectSpecific surface areaen
dcterms.subjectBETen
dcterms.subject.materiaÓptica, Acústicaes

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